Example of free purchase order forms
Emailmeform -- This website provides a tool to create a free purchase order forms online by yourself. You can choose as many different fidles as you want. It looks fast, easy and quite useful but comes in an online form.
Megadox -- Free purchase order forms to download and. The form comes in MSword which might be more effective for general usage.
Filespack -- Download free purchase order forms. It's a 20 days trial software to help you generate purchase order without database. You may have to pay after the free trial period.