Paid purchase order forms.
You usually receive a better return when you pay.
Findlegalforms -- A very good website selling (yeah it's not free.) all kind of legal forms, including purchase order forms. It's not free but it's quite cheap when considering that you can use the form as many times as you want.
Allbusiness -- Download all business forms including "purchase order forms". It provides all kind of form since you start the business until you want to terminate it.
Envision-sbs -- more than 1000 business document forms that you can down load and print immedietly
Biztree -- Another good website to download purchase order forms and other necessary forms for your business.